Dreamweaver and PHP

Yes, you can use Dreamweaver to create PHP pages so this may be a good choice of development environment.

Personally I haven't used it but from what I can find on the web it looks straightforward enough:

http://webdesign.about.com/od/dreamweaverhowtos/ss/dw_dynamic_site.htm

http://www.articlesbase.com/business-articles/using-php-buttons-in-dreamweaver-74804.html